Information card for entry 4318047

Structure parameters

• Chemical name: [TpRu{P(OMe)3}2NH2Ph][OTf] (5).
• Formula: C22 H35 B F3 N7 O9 P2 Ru S
• Calculated formula: C22 H35 B F3 N7 O9 P2 Ru S
• Title of publication: Influence of Filled dπ-Manifold and L/L' Ligands on the Structure, Basicity, and Bond Rotations of the Octahedral and d6 Amido Complexes TpRu(L)(L')(NHPh) (Tp = Hydridotris(pyrazolyl)borate; L = L' = PMe3or P(OMe)3, or L = CO and L' = PPh3): Solid-State Structures of [TpRu(PMe3)2(NH2Ph)][OTf], [TpRu{P(OMe)3}2(NH2Ph)][OTf], and TpRu{P(OMe)3}2(NHPh)
• Authors of publication: David Conner; K. N. Jayaprakash; T. Brent Gunnoe; Paul D. Boyle
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 3042 - 3049
• a: 9.1753 ± 0.0006 Å
• b: 23.7851 ± 0.0018 Å
• c: 15.3015 ± 0.001 Å
• α: 90°
• β: 92.307 ± 0.005°
• γ: 90°
• Cell volume: 3336.6 ± 0.4 ų
• Cell temperature: 148 K
• Ambient diffraction temperature: 148 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.025
• Residual factor for significantly intense reflections: 0.025
• Weighted residual factors for all reflections: 0.03
• Weighted residual factors for significantly intense reflections: 0.03
• Goodness-of-fit parameter for significantly intense reflections: 1.61
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MolybdenumKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No