Information card for entry 4318155

Structure parameters

• Common name: [Rh2(F-O2But)8(DMF)2].toluene
• Formula: C29 H22 F28 N2 O10 Rh2
• Calculated formula: C29 H22 F28 N2 O10 Rh2
• Title of publication: Carbon Dioxide as a Solubility "Switch" for the Reversible Dissolution of Highly Fluorinated Complexes and Reagents in Organic Solvents: Application to Crystallization
• Authors of publication: Philip G. Jessop; Marilyn M. Olmstead; Christopher D. Ablan; Megan Grabenauer; Daniel Sheppard; Charles A. Eckert; Charles L. Liotta
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 3463 - 3468
• a: 10.559 ± 0.002 Å
• b: 10.578 ± 0.002 Å
• c: 22.015 ± 0.004 Å
• α: 82.103 ± 0.008°
• β: 82.239 ± 0.007°
• γ: 63.296 ± 0.008°
• Cell volume: 2168.3 ± 0.7 ų
• Cell temperature: 92 ± 2 K
• Ambient diffraction temperature: 92 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0966
• Residual factor for significantly intense reflections: 0.0684
• Weighted residual factors for significantly intense reflections: 0.1633
• Weighted residual factors for all reflections included in the refinement: 0.1769
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No