Information card for entry 4318521

Structure parameters

• Common name: [Yb(Pyr)6][Co(CO)4]2.Pyr
• Chemical name: hexa(pyridine)ytterbium(II) tetracarbonylcobaltate pyridine
• Formula: C43 H35 Co2 N7 O8 Yb
• Calculated formula: C43 H35 Co2 N7 O8 Yb
• SMILES: [Yb]([n]1ccccc1)([n]1ccccc1)([n]1ccccc1)([n]1ccccc1)([n]1ccccc1)[n]1ccccc1.[Co](C#[O])(C#[O])(C#[O])C#[O].[Co](C#[O])(C#[O])(C#[O])C#[O].n1ccccc1
• Title of publication: Lanthanide-Transition-Metal Carbonyl Complexes. 1. Syntheses and Structures of Ytterbium(II) Solvent-Separated Ion Pairs and Isocarbonyl Polymeric Arrays of Tetracarbonylcobaltate
• Authors of publication: Christine E. Plečnik; Shengming Liu; Jianping Liu; Xuenian Chen; Edward A. Meyers; Sheldon G. Shore
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 4936 - 4943
• a: 11.171 ± 0.001 Å
• b: 11.925 ± 0.001 Å
• c: 33.978 ± 0.001 Å
• α: 90°
• β: 95.1 ± 0.01°
• γ: 90°
• Cell volume: 4508.4 ± 0.6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0443
• Residual factor for significantly intense reflections: 0.0309
• Weighted residual factors for significantly intense reflections: 0.0705
• Weighted residual factors for all reflections included in the refinement: 0.0748
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No