Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1-3)
Authors of publication
Augusto Cingolani; Effendy; Maura Pellei; Claudio Pettinari; Carlo Santini; Brian W. Skelton; Allan H. White
Journal of publication
Inorganic Chemistry
Year of publication
2002
Journal volume
41
Pages of publication
6633 - 6645
a
18.5301 ± 0.0007 Å
b
14.084 ± 0.0005 Å
c
14.1379 ± 0.0005 Å
α
61.087 ± 0.001°
β
79.547 ± 0.001°
γ
77.195 ± 0.001°
Cell volume
3137.5 ± 0.2 Å3
Cell temperature
150 K
Ambient diffraction temperature
150 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.063
Residual factor for significantly intense reflections
0.03
Weighted residual factors for all reflections
0.026
Weighted residual factors for all reflections included in the refinement
0.023
Goodness-of-fit parameter for all reflections
0.961
Goodness-of-fit parameter for all reflections included in the refinement
