Information card for entry 4319018

Structure parameters

• Common name: PhetPhosRh
• Formula: C30 H64 B F4 N4 P2 Rh Si2
• Calculated formula: C30 H64 B F4 N4 P2 Rh Si2
• SMILES: [Rh]1234([P]5(N(C(C)(C)C)[Si](N5C(C)(C)C)(C)C)CC[P]51N(C(C)(C)C)[Si](N5C(C)(C)C)(C)C)[CH]1CC[CH]2=[CH]3CC[CH]4=1.[B](F)(F)(F)[F-]
• Title of publication: Inorganic Heterocyclic Bis(phosphines): Syntheses and Structures of a 1,2-Bis(diazasilaphosphetidino)ethane and Its Nickel, Molybdenum, and Rhodium Complexes
• Authors of publication: Ingo Schranz; Graham R. Lief; Steven J. Midstokke; Lothar Stahl
• Journal of publication: Inorganic Chemistry
• Year of publication: 2002
• Journal volume: 41
• Pages of publication: 6919 - 6927
• a: 21.064 ± 0.002 Å
• b: 18.379 ± 0.001 Å
• c: 10.068 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3897.7 ± 1.2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0395
• Weighted residual factors for significantly intense reflections: 0.0999
• Weighted residual factors for all reflections included in the refinement: 0.1062
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No