Information card for entry 4319273

Structure parameters

• Chemical name: [{(2-NC5H4)CMe(CH2NSiMe3)2}Ti(N-2,6-C6H3-i-Pr2)]
• Formula: C27 H46 N4 Si2 Ti
• Calculated formula: C27 H46 N4 Si2 Ti
• SMILES: [Ti]12(=Nc3c(cccc3C(C)C)C(C)C)N([Si](C)(C)C)CC(c3[n]2cccc3)(CN1[Si](C)(C)C)C
• Title of publication: Group 4 Imido Complexes Stabilized by a Tridentate Diamido-Donor Ligand
• Authors of publication: Alexander J. Blake; Philip E. Collier; Lutz H. Gade; Philip Mountford; Julian Lloyd; Stephen M. Pugh; Martin Schubart; Michael E. G. Skinner; Dominique J. M. Trösch
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 870 - 877
• a: 10.773 ± 0.0004 Å
• b: 15.922 ± 0.0006 Å
• c: 18.708 ± 0.0004 Å
• α: 90°
• β: 103.294 ± 0.002°
• γ: 90°
• Cell volume: 3122.95 ± 0.18 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0372
• Weighted residual factors for significantly intense reflections: 0.0404
• Goodness-of-fit parameter for significantly intense reflections: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No