Information card for entry 4320367

Structure parameters

• Common name: [NacNacGe][OH{B(C6F5)3}2]
• Formula: C65 H42 B2 F30 Ge N2 O
• Calculated formula: C65 H42 B2 F30 Ge N2 O
• SMILES: [Ge]1N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)c1c(cccc1C(C)C)C(C)C.[OH]([B](c1c(F)c(F)c(F)c(F)c1F)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F)[B](c1c(F)c(F)c(F)c(F)c1F)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Characterization and Bonding of the Cation [Ge{N(C6H3-2,6-i-Pr2)CMe}2CH]+: Comparison with the Isoelectronic Ga{N(C6H3-2,6-i-Pr2)CMe}2CH
• Authors of publication: Matthias Stender; Andrew D. Phillips; Philip P. Power
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 5314 - 5315
• a: 20.2586 ± 0.0007 Å
• b: 17.5332 ± 0.0006 Å
• c: 18.5394 ± 0.0006 Å
• α: 90°
• β: 109.736 ± 0.001°
• γ: 90°
• Cell volume: 6198.3 ± 0.4 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.147
• Residual factor for significantly intense reflections: 0.0561
• Weighted residual factors for significantly intense reflections: 0.1021
• Weighted residual factors for all reflections included in the refinement: 0.1341
• Goodness-of-fit parameter for all reflections included in the refinement: 0.992
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No