Information card for entry 4321838

Structure parameters

• Chemical name: bis[tris(2,2'-bipyridine)osmium(II)] [hexacyanochromate(III)] chloride octahydrate
• Formula: C66 H48 Cl Cr N18 O8 Os2
• Calculated formula: C66 H48 Cl Cr N18 O8 Os2
• SMILES: [Cr](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Os]123([n]4ccccc4c4[n]1cccc4)([n]1ccccc1c1[n]2cccc1)[n]1ccccc1c1[n]3cccc1.[Os]123([n]4ccccc4c4[n]1cccc4)([n]1ccccc1c1[n]2cccc1)[n]1ccccc1c1[n]3cccc1.O.O.O.O.O.O.O.O.O.[Cl-]
• Title of publication: Crystal Structure and Energy Transfer in Double-Complex Salts Composed of Tris(2,2'-bipyridine)ruthenium(II) or Tris(2,2'-bipyridine)osmium(II) and Hexacyanochromate(III)
• Authors of publication: Takuhiro Otsuka; Naoto Takahashi; Naoki Fujigasaki; Akiko Sekine; Yuji Ohashi; Youkoh Kaizu
• Journal of publication: Inorganic Chemistry
• Year of publication: 1999
• Journal volume: 38
• Pages of publication: 1340 - 1347
• a: 22.384 ± 0.004 Å
• b: 13.827 ± 0.004 Å
• c: 22.186 ± 0.003 Å
• α: 90°
• β: 90.7 ± 0.02°
• γ: 90°
• Cell volume: 6866 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.0812
• Residual factor for significantly intense reflections: 0.0788
• Weighted residual factors for all reflections: 0.2075
• Weighted residual factors for significantly intense reflections: 0.193
• Goodness-of-fit parameter for all reflections: 1.072
• Goodness-of-fit parameter for significantly intense reflections: 1.072
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No