Information card for entry 4323032

Structure parameters

• Formula: C89 H102 B2 Cl2 Fe Ir4 S4
• Calculated formula: C178 H204 B4 Cl4 Fe2 Ir8 S8
• Title of publication: Metal-Metal Bonding in Pentanuclear Bow-Tie Metal Sulfido Clusters. Synthetic and Structural Studies on the Cationic Pentanuclear Clusters [(Cp*Ir)2(μ3-S)2M(μ3-S)2(IrCp*)2]n+ (M = Fe, Co, Ni; n = 1, 2)
• Authors of publication: Zhen Tang; Yasuo Nomura; Shigeki Kuwata; Youichi Ishii; Yasushi Mizobe; Masanobu Hidai
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 4909 - 4920
• a: 16.899 ± 0.002 Å
• b: 23.646 ± 0.005 Å
• c: 11.4 ± 0.002 Å
• α: 101.47 ± 0.02°
• β: 102.12 ± 0.01°
• γ: 76 ± 0.01°
• Cell volume: 4268.6 ± 1.3 ų
• Cell temperature: 23 K
• Ambient diffraction temperature: 23 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.048
• Weighted residual factors for significantly intense reflections: 0.037
• Goodness-of-fit parameter for significantly intense reflections: 1.87
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKalpha
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No