Information card for entry 4323150

Structure parameters

• Formula: C16.5 H33.5 Cl6 S3 W2
• Calculated formula: C16.5 H33.5 Cl6 S3 W2
• Title of publication: Syntheses, Crystal Structures, Spectroscopic Characterization, and Electrochemical Studies of the Ditungsten(III) Complexes Cl~3~W(μ-L)~3~WCl~3~ and [Cl~3~W(μ-L)~2~(μ-Cl)WCl~3~]^-^ (L = 1,4-Dithiane, 1,4-Thioxane, pms = Pentamethylene Sulfide). C-S Bond Cleavage of the Bridging Thioether(s) in Cl~3~W(μ-L)~3~WCl~3~
• Authors of publication: P. Michael Boorman; Naomi L. Langdon; Vivian J. Mozol; Masood Parvez; Glenn P. A. Yap
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 6023 - 6029
• a: 11.874 ± 0.004 Å
• b: 21.823 ± 0.003 Å
• c: 12.545 ± 0.003 Å
• α: 90°
• β: 100.46 ± 0.03°
• γ: 90°
• Cell volume: 3196.7 ± 1.4 ų
• Cell temperature: 200 K
• Ambient diffraction temperature: 200.2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0512
• Residual factor for significantly intense reflections: 0.0512
• Weighted residual factors for all reflections: 0.0491
• Weighted residual factors for significantly intense reflections: 0.0491
• Goodness-of-fit parameter for all reflections: 2.034
• Goodness-of-fit parameter for significantly intense reflections: 2.034
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No