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Information card for entry 4323274
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Jmol._Canvas2D (Jmol) "jmolApplet0"[x]
Coordinates | 4323274.cif |
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Original paper (by DOI) | HTML |
Common name | cis-Tetrachloro-bis(t-butylamido)-dimethylphosphinoethan ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(t-butylamido)-(cis)-1,2- dimethylphosphinoethan ditungsten(III) |
Formula | C14 H36 Cl4 N2 P2 W2 |
Calculated formula | C14 H36 Cl4 N2 P2 W2 |
SMILES | [W]1([W]([P](CC[P]1(C)C)(C)C)(Cl)(Cl)NC(C)(C)C)(Cl)(Cl)NC(C)(C)C |
Title of publication | W2Cl4(NHR)2(PR'3)2 Molecules. 3. Bidentate Phosphine Complexes of Bis(tert-butylamido)tetrachloroditungsten. Preparation and Structural Characterization of cis,cis-W2Cl4(NHCMe3)2(L-L) (L-L = dmpm, dmpe, dppm, dppe) |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 80 - 85 |
a | 14.144 ± 0.002 Å |
b | 11.991 ± 0.001 Å |
c | 15.662 ± 0.002 Å |
α | 90° |
β | 109.5 ± 0.01° |
γ | 90° |
Cell volume | 2503.9 ± 0.5 Å3 |
Cell temperature | 293 ± 2 K |
Ambient diffraction temperature | 293 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0424 |
Residual factor for significantly intense reflections | 0.0343 |
Weighted residual factors for all reflections | 0.095 |
Weighted residual factors for significantly intense reflections | 0.0878 |
Goodness-of-fit parameter for all reflections | 1.103 |
Goodness-of-fit parameter for significantly intense reflections | 1.119 |
Diffraction radiation wavelength | 1.54184 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4323274.html
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