Information card for entry 4323310

Structure parameters

• Formula: C32 H34 Au2 B10 P2 S2
• Calculated formula: C32 H34 Au2 B10 P2 S2
• SMILES: [Au]1[P](c2ccccc2)(c2ccccc2)c2c(cccc2)[P](c2ccccc2)(c2ccccc2)[Au]S[C]2345[BH]678[BH]9%10%11[BH]%12%13%14[BH]2%15([BH]2%16%13[BH]%13%10%12[BH]%1069[BH]647[BH]23%15[BH]%16%13%106)[C]58%11%14S1
• Title of publication: Synthesis and Characterization of Gold(I) Complexes with the Ligand 1,2-Dithiolate-o-carborane. Crystal Structures of [Au~2~(μ-S~2~C~2~B~10~H~10~)(PPh~3~)~2~], [Au~2~(μ-S~2~C~2~B~10~H~10~)(μ-{(PPh~2~)~2~(CHCH)}], and [Au~2~(μ-S~2~C~2~B~10~H~10~)(μ-{(PPh~2~)~2~)(C~6~H~4~)}]
• Authors of publication: Olga Crespo; M. Concepción Gimeno; Peter G. Jones; Birte Ahrens; Antonio Laguna
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 495 - 500
• a: 11.921 ± 0.003 Å
• b: 12.894 ± 0.004 Å
• c: 14.342 ± 0.004 Å
• α: 114.113 ± 0.015°
• β: 91.63 ± 0.02°
• γ: 115.01 ± 0.012°
• Cell volume: 1768.7 ± 1 ų
• Cell temperature: 143 ± 2 K
• Ambient diffraction temperature: 143 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0462
• Residual factor for significantly intense reflections: 0.0357
• Weighted residual factors for all reflections: 0.0883
• Weighted residual factors for significantly intense reflections: 0.0793
• Goodness-of-fit parameter for all reflections: 1.046
• Goodness-of-fit parameter for significantly intense reflections: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No