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Information card for entry 4323329
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Coordinates | 4323329.cif |
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Original paper (by DOI) | HTML |
Common name | trans,trans-Tetrachloro-bis(diethylamido)-bis(diphenylphosphino)ethane ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(diethylamido)-(trans,trans)-bis(diphenyl- phosphino)ethane ditungsten(III) |
Formula | C41 H52 Cl4 N2 P2 W2 |
Calculated formula | C41 H52 Cl4 N2 P2 W2 |
Title of publication | W2Cl4(NR2)2(PR'3)2 Molecules. 5. Preparation and Characterization of W2Cl4(NEt2)2(L-L) (L-L = dmpm, dmpe, dppe), W2Cl4(NBu2)2(L-L) (L-L = dmpm, dmpe), and W2Cl4(NHex2)2(dmpm). First Complexes with Bridging Diphosphine Ligands in a cis,trans-Stereochemistry |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 902 - 912 |
a | 16.396 ± 0.003 Å |
b | 10.104 ± 0.002 Å |
c | 26.68 ± 0.002 Å |
α | 90° |
β | 92.22 ± 0.01° |
γ | 90° |
Cell volume | 4416.6 ± 1.2 Å3 |
Cell temperature | 293 ± 2 K |
Ambient diffraction temperature | 293 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0561 |
Residual factor for significantly intense reflections | 0.0423 |
Weighted residual factors for all reflections | 0.1172 |
Weighted residual factors for significantly intense reflections | 0.1079 |
Goodness-of-fit parameter for all reflections | 1.053 |
Goodness-of-fit parameter for significantly intense reflections | 1.057 |
Diffraction radiation wavelength | 1.54184 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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