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Information card for entry 4323331
Preview
Coordinates | 4323331.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | cis,cis-Tetrachloro-bis(diethylamido)-bis(dimethyl- phosphino)methane ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(diethylamido)-(cis,cis)- 1,2-bis(dimethylphosphino)methane ditungsten(III) |
Formula | C13 H34 Cl4 N2 P2 W2 |
Calculated formula | C13 H34 Cl4 N2 P2 W2 |
SMILES | [W]1([W]([P](C[P]1(C)C)(C)C)(Cl)(Cl)N(CC)CC)(Cl)(Cl)N(CC)CC |
Title of publication | W2Cl4(NR2)2(PR'3)2 Molecules. 5. Preparation and Characterization of W2Cl4(NEt2)2(L-L) (L-L = dmpm, dmpe, dppe), W2Cl4(NBu2)2(L-L) (L-L = dmpm, dmpe), and W2Cl4(NHex2)2(dmpm). First Complexes with Bridging Diphosphine Ligands in a cis,trans-Stereochemistry |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 902 - 912 |
a | 8.76 ± 0.003 Å |
b | 21.028 ± 0.008 Å |
c | 12.778 ± 0.005 Å |
α | 90° |
β | 91.77 ± 0.03° |
γ | 90° |
Cell volume | 2352.7 ± 1.5 Å3 |
Cell temperature | 293 ± 2 K |
Ambient diffraction temperature | 293 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0633 |
Residual factor for significantly intense reflections | 0.0587 |
Weighted residual factors for all reflections | 0.1702 |
Weighted residual factors for significantly intense reflections | 0.1656 |
Goodness-of-fit parameter for all reflections | 1.111 |
Goodness-of-fit parameter for significantly intense reflections | 1.128 |
Diffraction radiation wavelength | 1.54184 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4323331.html
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