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Information card for entry 4323333
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Coordinates | 4323333.cif |
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Original paper (by DOI) | HTML |
Common name | cis,cis-Tetrachloro-bis(dibutylamido)-bis(dimethylphosphino)methane ditungsten(III) |
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Chemical name | 1,1,2,2-Tetrachloro-1,2-bis(dibutylamido)-(cis,cis)-bis(dimethyl- phosphino)methane ditungsten(III) |
Formula | C21 H50 Cl4 N2 P2 W2 |
Calculated formula | C21 H50 Cl4 N2 P2 W2 |
Title of publication | W2Cl4(NR2)2(PR'3)2 Molecules. 5. Preparation and Characterization of W2Cl4(NEt2)2(L-L) (L-L = dmpm, dmpe, dppe), W2Cl4(NBu2)2(L-L) (L-L = dmpm, dmpe), and W2Cl4(NHex2)2(dmpm). First Complexes with Bridging Diphosphine Ligands in a cis,trans-Stereochemistry |
Authors of publication | F. Albert Cotton; Evgeny V. Dikarev; Wai-Yeung Wong |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 902 - 912 |
a | 18.011 ± 0.004 Å |
b | 17.221 ± 0.004 Å |
c | 21.264 ± 0.006 Å |
α | 90° |
β | 103.33 ± 0.02° |
γ | 90° |
Cell volume | 6418 ± 3 Å3 |
Cell temperature | 213 ± 2 K |
Ambient diffraction temperature | 213 ± 2 K |
Number of distinct elements | 6 |
Space group number | 15 |
Hermann-Mauguin space group symbol | C 1 2/c 1 |
Hall space group symbol | -C 2yc |
Residual factor for all reflections | 0.1328 |
Residual factor for significantly intense reflections | 0.0608 |
Weighted residual factors for all reflections | 0.1495 |
Weighted residual factors for significantly intense reflections | 0.1254 |
Goodness-of-fit parameter for all reflections | 0.916 |
Goodness-of-fit parameter for significantly intense reflections | 1.108 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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