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Information card for entry 4323363
Preview
Coordinates | 4323363.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | Tetraphenylphosphonium tris(trifluoromethyl)methylargenate(III) |
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Formula | C28 H23 Ag F9 P |
Calculated formula | C28 H23 Ag F9 P |
SMILES | [Ag](C)(C(F)(F)F)(C(F)(F)F)C(F)(F)F.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Preparation and NMR Spectra of the (Trifluoromethyl)argentates(III) [Ag(CF~3~)~n~X~4-n~]^-^, with X = CN (n= 1-3), CH~3~, C\τbCC~6~H~11~, Cl, Br (n= 2, 3), and I (n= 3), and of Related Silver(III) Compounds. Structures of [PPh~4~][trans-Ag(CF~3~)~2~(CN)~2~] and [PPh~4~][Ag(CF~3~)~3~CH~3~]. |
Authors of publication | Reint Eujen; Berthold Hoge; David J. Brauer |
Journal of publication | Inorganic Chemistry |
Year of publication | 1997 |
Journal volume | 36 |
Pages of publication | 1464 - 1475 |
a | 24.941 ± 0.003 Å |
b | 7.2629 ± 0.0006 Å |
c | 14.9985 ± 0.0014 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 2716.9 ± 0.5 Å3 |
Cell temperature | 291 ± 2 K |
Ambient diffraction temperature | 291 ± 2 K |
Number of distinct elements | 5 |
Space group number | 29 |
Hermann-Mauguin space group symbol | P c a 21 |
Hall space group symbol | P 2c -2ac |
Residual factor for all reflections | 0.038 |
Residual factor for significantly intense reflections | 0.032 |
Weighted residual factors for all reflections | 0.0824 |
Weighted residual factors for significantly intense reflections | 0.0785 |
Goodness-of-fit parameter for all reflections | 1.043 |
Goodness-of-fit parameter for significantly intense reflections | 1.074 |
Diffraction radiation wavelength | 1.54184 Å |
Diffraction radiation type | CuKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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