Information card for entry 4323437

Structure parameters

• Common name: trans-Mo(Te)~2~(dppee)~2~
• Chemical name: trans-bis(cis-1,2-bis(diphenylphosphino)ethylene-P,P')-di-tellurido- molybdenum(IV)
• Formula: C52 H44 Mo P4 Te2
• Calculated formula: C52 H44 Mo P4 Te2
• SMILES: [Mo]12(=[Te])(=[Te])([P](C=C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](C=C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mononuclear Molybdenum(IV) Complexes with Two Multiply Bonded Chalcogen Ligands in Trans Configuration and Chelating Biphosphine Ligands
• Authors of publication: F. Albert Cotton; Günter Schmid
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 2267 - 2278
• a: 12.681 ± 0.004 Å
• b: 19.28 ± 0.005 Å
• c: 10.454 ± 0.003 Å
• α: 104.6 ± 0.02°
• β: 111.61 ± 0.02°
• γ: 75.12 ± 0.02°
• Cell volume: 2261 ± 1.2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1188
• Residual factor for significantly intense reflections: 0.05
• Weighted residual factors for all reflections: 0.1425
• Weighted residual factors for significantly intense reflections: 0.117
• Goodness-of-fit parameter for all reflections: 1.047
• Goodness-of-fit parameter for significantly intense reflections: 1.087
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No