Information card for entry 4323450

Structure parameters

• Chemical name: Berylium-N,N'-Bis(trimethylsilyl)-aminodiphenylphosphinimid
• Formula: C36 H56 Be N4 P2 Si4
• Calculated formula: C36 H56 Be N4 P2 Si4
• SMILES: [Ba]12([N]([Si](C)(C)C)=P(N1[Si](C)(C)C)(c1ccccc1)c1ccccc1)[N]([Si](C)(C)C)=P(N2[Si](C)(C)C)(c1ccccc1)c1ccccc1
• Title of publication: Syntheses and Structures of [(THF)nM{(NSiMe3)2PPh2}2] Complexes (M = Be, Mg, Ca, Sr, Ba;n= 0-2): Deviation of Alkaline Earth Metal Cations from the Plane of an Anionic Ligand
• Authors of publication: Roland Fleischer; Dietmar Stalke
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 2413 - 2419
• a: 18.845 ± 0.008 Å
• b: 11.474 ± 0.003 Å
• c: 19.836 ± 0.008 Å
• α: 90°
• β: 100.92 ± 0.03°
• γ: 90°
• Cell volume: 4211 ± 3 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0287
• Residual factor for significantly intense reflections: 0.0264
• Weighted residual factors for all reflections: 0.0671
• Weighted residual factors for significantly intense reflections: 0.0658
• Goodness-of-fit parameter for all reflections: 1.032
• Goodness-of-fit parameter for significantly intense reflections: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKa
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No