Information card for entry 4323577

Structure parameters

• Formula: C16 H17 Bi2 Cl2 Fe2 N O6
• Calculated formula: C16 H17 Bi2 Cl2 Fe2 N O6
• Title of publication: Halide Ion Addition to Bismuth-Containing Iron Carbonyl Compounds: Synthesis and Characterization of the Two Bridged-Butterfly Cluster Compounds [Et4N][(μ-H)Fe2(CO)6Bi2{μ-Fe(CO)4}] and [{PhCH2NMe3}{(μ-H)Fe2(CO)6Bi2(μ-Cl)2}]∞and Stabilization of Reduced-Hypervalent Bismuth Centers by Coordination to a Metal Center in [PhCH2NMe3]3[Bi3Cl4(μ-Cl)4{Fe(CO)3}]
• Authors of publication: Jeffrey R. Eveland; Jean-Yves Saillard; Kenton H. Whitmire
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 4387 - 4396
• a: 7.864 ± 0.002 Å
• b: 22.465 ± 0.004 Å
• c: 13.797 ± 0.003 Å
• α: 90°
• β: 105.96 ± 0.03°
• γ: 90°
• Cell volume: 2343.5 ± 1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0558
• Residual factor for significantly intense reflections: 0.0285
• Weighted residual factors for all reflections: 0.0631
• Weighted residual factors for significantly intense reflections: 0.0556
• Goodness-of-fit parameter for all reflections: 1.016
• Goodness-of-fit parameter for significantly intense reflections: 1.045
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No