Information card for entry 4323788

Structure parameters

• Formula: C88 H104 Au2 B18 O3 P6
• Calculated formula: C88 H80 Au2 B18 O3 P6
• Title of publication: Gold(I) Complexes with the nido-Diphosphino Ligand [7,8-(Ph2P)2-7,8-C2B9H10]-. Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh2)2C2B9H10}(PPh3)].CH2Cl2 and [Au2{(PPh2)2C2B9H10}2{(PPh2)2(CH2)3}].3Me2CO
• Authors of publication: Olga Crespo; M. Concepción Gimeno; Peter G. Jones; Antonio Laguna
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 1361 - 1366
• a: 13.432 ± 0.003 Å
• b: 18.888 ± 0.003 Å
• c: 20.021 ± 0.003 Å
• α: 78.56 ± 0.02°
• β: 72.02 ± 0.02°
• γ: 75.31 ± 0.02°
• Cell volume: 4633.5 ± 1.6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0964
• Residual factor for significantly intense reflections: 0.0533
• Weighted residual factors for all reflections: 0.1124
• Weighted residual factors for significantly intense reflections: 0.0936
• Goodness-of-fit parameter for all reflections: 1.081
• Goodness-of-fit parameter for significantly intense reflections: 1.102
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No