Information card for entry 4323925

Structure parameters

• Formula: C60 H66 N10 O16 Rh2
• Calculated formula: C60 H66 N10 O16 Rh2
• SMILES: [Rh]1234([Rh](N5C(N(C[C@H]5C(=O)OC)C(=O)CCc5ccccc5)=[O]1)([O]=C1N2[C@@H](CN1C(=O)CCc1ccccc1)C(=O)OC)([O]=C1N3[C@@H](CN1C(=O)CCc1ccccc1)C(=O)OC)(N1C(N(C[C@H]1C(=O)OC)C(=O)CCc1ccccc1)=[O]4)[N]#CC)[N]#CC
• Title of publication: Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl 1-acyl-2-oxoimidazolidine-4(S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations
• Authors of publication: Michael P. Doyle; Qi-Lin Zhou; Conrad E. Raab; Gregory H. P. Roos; Stanley H. Simonsen; Vincent Lynch
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 6064 - 6073
• a: 11.589 ± 0.001 Å
• b: 12.225 ± 0.001 Å
• c: 21.802 ± 0.002 Å
• α: 90°
• β: 94.429 ± 0.008°
• γ: 90°
• Cell volume: 3079.6 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0763
• Residual factor for significantly intense reflections: 0.0455
• Weighted residual factors for all reflections: 0.0772
• Weighted residual factors for significantly intense reflections: 0.069
• Goodness-of-fit parameter for all reflections: 1.004
• Goodness-of-fit parameter for significantly intense reflections: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No