Information card for entry 4323951

Structure parameters

• Formula: C58 H42 Cl2 F10 N2 O4 P2 Pt
• Calculated formula: C58 H42 Cl2 F10 N2 O4 P2 Pt
• SMILES: [Pt](Cl)(Cl)([NH]=C(C(C(=O)OCC)=P(c1ccccc1)(c1ccccc1)c1ccccc1)c1c(c(c(c(c1F)F)F)F)F)[N](C(=C\C(=O)OCC)\c1c(c(c(c(c1F)F)F)F)F)=P(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Platinum-Assisted Addition of Carbonyl-Stabilized Phosphorus Ylides to Pentafluorobenzonitrile and Acetonitrile To Give Platinum(II) Complexes Containing Iminophosphorane and/or N-Bonded β-Imino Phosphorus Ylide Ligands. Crystal and Molecular Structures of trans-[PtCl2{E-NHC(C6F5)C(PPh3)C(O)Me}2] and trans-[PtCl2{E-N(PPh3)C(C6F5)CHCO2Et}{E-NHC(C6F5)C(PPh3)CO2Et}]
• Authors of publication: José Vicente; María Teresa Chicote; Michael A. Beswick; M. Carmen Ramirez de Arellano
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 6592 - 6598
• a: 16.4 ± 0.008 Å
• b: 14.354 ± 0.007 Å
• c: 23.221 ± 0.012 Å
• α: 90°
• β: 92.42 ± 0.02°
• γ: 90°
• Cell volume: 5461 ± 5 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0399
• Residual factor for significantly intense reflections: 0.0246
• Weighted residual factors for all reflections: 0.1493
• Weighted residual factors for significantly intense reflections: 0.0557
• Goodness-of-fit parameter for all reflections: 1.066
• Goodness-of-fit parameter for significantly intense reflections: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No