Information card for entry 4324155

Structure parameters

• Formula: C31 H31 F12 N9 P2 Ru
• Calculated formula: C31 H31 F12 N9 P2 Ru
• Title of publication: Changing the Role of 2,2'-Bipyridine from Secondary Ligand to Protagonist in [Ru(bpy)2(N-N)]2+ Complexes: Low-Energy, Red Emission from a Ruthenium(II)-to-2,2'-Bipyridine 3MLCT State
• Authors of publication: Samik Nag; Janaina G. Ferreira; Ludwig Chenneberg; Philippe Dauphin Ducharme; Garry S. Hanan; Giuseppina La Ganga; Scolastica Serroni; Sebastiano Campagna
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 7 - 9
• a: 20.4021 ± 0.0008 Å
• b: 10.5565 ± 0.0004 Å
• c: 16.4117 ± 0.0007 Å
• α: 90°
• β: 95.787 ± 0.002°
• γ: 90°
• Cell volume: 3516.7 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0415
• Residual factor for significantly intense reflections: 0.0362
• Weighted residual factors for significantly intense reflections: 0.0971
• Weighted residual factors for all reflections included in the refinement: 0.0999
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No