Information card for entry 4325149

Structure parameters

• Common name: tetrakis(triisopropylphosphino)-hexakis(copper-phenylselenolate)
• Chemical name: tris(μ~3~-phenylselenido)-tris(μ~2~-phenylselenido) -tetrakis(triisopropylphosphine)-hexa-copper pentane solvate
• Formula: C72 H114 Cu6 P4 Se6
• Calculated formula: C76.995 H114 Cu6 P4 Se6
• Title of publication: Trialkylphosphine-Stabilized Copper(I) Phenylchalcogenolate Complexes - Crystal Structures and Copper-Chalcogenolate Bonding
• Authors of publication: Oliver Kluge; Katharina Grummt; Ralf Biedermann; Harald Krautscheid
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 4742 - 4752
• a: 14.9225 ± 0.0007 Å
• b: 24.362 ± 0.0011 Å
• c: 27.1525 ± 0.0012 Å
• α: 71.435 ± 0.003°
• β: 88.298 ± 0.004°
• γ: 71.704 ± 0.004°
• Cell volume: 8857.3 ± 0.8 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1114
• Residual factor for significantly intense reflections: 0.0473
• Weighted residual factors for significantly intense reflections: 0.0837
• Weighted residual factors for all reflections included in the refinement: 0.0984
• Goodness-of-fit parameter for all reflections included in the refinement: 0.833
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No