Information card for entry 4325296

Structure parameters

• Common name: [Rh2(tfepma)2(CNtBu)3(mu-H)](OTs)
• Formula: C40 H57 F24 N5 O11 P4 Rh2 S
• Calculated formula: C40 H57 F24 N5 O11 P4 Rh2 S
• Title of publication: Redox Chemistry, Acid Reactivity, and Hydrogenation Reactions of Two-Electron Mixed Valence Diiridium and Dirhodium Complexes
• Authors of publication: Thomas S. Teets; Timothy R. Cook; Brian D. McCarthy; Daniel G. Nocera
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 5223 - 5233
• a: 12.9771 ± 0.0014 Å
• b: 22.103 ± 0.002 Å
• c: 22.523 ± 0.002 Å
• α: 90°
• β: 93.474 ± 0.002°
• γ: 90°
• Cell volume: 6448.5 ± 1.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1133
• Residual factor for significantly intense reflections: 0.0963
• Weighted residual factors for significantly intense reflections: 0.2099
• Weighted residual factors for all reflections included in the refinement: 0.2192
• Goodness-of-fit parameter for all reflections included in the refinement: 1.179
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No