Information card for entry 4326107

Structure parameters

• Common name: Tris{η^3^-μ-1,3-bis[(2-pyridyl)methyl]-4,5-dihydroimidazol-2- ylidene}trisilver(I) tetrafluoroborate acetonitrile tetrasolvate
• Chemical name: Triangulo-tris{η^3^-μ~2~-1,3-bis[(2-pyridyl-κN)methyl]- 4,5-dihydro-2<i>H</i>-imidazol-2-ylidene-κC}trisilver(I) 3(Ag—Ag) tetrafluoroborate ethanenitrile tetrasolvate
• Formula: C53 H60 Ag3 B3 F12 N16
• Calculated formula: C53 H59.97 Ag3 B3 F12 N16
• Title of publication: Modulation of Metal-Metal Separations in a Series of Ag(I) and Intensely Blue Photoluminescent Cu(I) NHC-Bridged Triangular Clusters
• Authors of publication: Vincent J. Catalano; Lyndsay B. Munro; Christoph E. Strasser; Ahmad F. Samin
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 8465 - 8476
• a: 13.0585 ± 0.0003 Å
• b: 13.0585 ± 0.0003 Å
• c: 21.1922 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 3129.63 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 159
• Hermann-Mauguin space group symbol: P 3 1 c
• Hall space group symbol: P 3 -2c
• Residual factor for all reflections: 0.0482
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.1097
• Weighted residual factors for all reflections included in the refinement: 0.1154
• Goodness-of-fit parameter for all reflections included in the refinement: 1.089
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No