Information card for entry 4326115

Structure parameters

• Common name: Tris{η^3^-μ-1,3-bis{[6-(methoxycarbonyl)-2-pyridyl]methyl}imidazol-2- ylidene}trisilver(I) tetrafluoroborate acetonitrile solvate
• Chemical name: Triangulo-tris{η^3^-μ~2~-1,3-bis{[6-(methoxycarbonyl)-2-pyridyl- κN]methyl}-2<i>H</i>-imidazol-2-ylidene-κC}trisilver(I) 3(Ag—Ag) tetrafluoroborate ethanenitrile solvate
• Formula: C59 H57 Ag3 B3 F12 N13 O12
• Calculated formula: C59 H54 Ag3 B3 F12 N13 O12
• Title of publication: Modulation of Metal-Metal Separations in a Series of Ag(I) and Intensely Blue Photoluminescent Cu(I) NHC-Bridged Triangular Clusters
• Authors of publication: Vincent J. Catalano; Lyndsay B. Munro; Christoph E. Strasser; Ahmad F. Samin
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 8465 - 8476
• a: 13.4196 ± 0.0003 Å
• b: 13.4196 ± 0.0003 Å
• c: 19.946 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 3110.75 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 163
• Hermann-Mauguin space group symbol: P -3 1 c
• Hall space group symbol: -P 3 2c
• Residual factor for all reflections: 0.0688
• Residual factor for significantly intense reflections: 0.0564
• Weighted residual factors for significantly intense reflections: 0.1311
• Weighted residual factors for all reflections included in the refinement: 0.1359
• Goodness-of-fit parameter for all reflections included in the refinement: 1.112
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No