Information card for entry 4326253

Structure parameters

• Formula: C40 H42 F18 N10 O2 Os2 P3
• Calculated formula: C40 H42 F18 N10 O2 Os2 P3
• SMILES: C1c2cccc[n]2[Os]2345([N]1(Cc1cccc[n]21)Cc1[n]3cccc1)O[Os]1235([N](Cc5cccc[n]15)(Cc1cccc[n]21)Cc1[n]3cccc1)O4.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].N#CC.[P](F)(F)(F)(F)(F)[F-].N#CC
• Title of publication: Synthesis and Properties of Oxo-carboxylato- and Dioxo-Bridged Diosmium Complexes of Tris(2-pyridylmethyl)amine
• Authors of publication: Hideki Sugimoto; Kazuhiro Kitayama; Kenji Ashikari; Chikako Matsunami; Naomi Ueda; Keisuke Umakoshi; Yuko Hosokoshi; Yoichi Sasaki; Shinobu Itoh
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 9014 - 9023
• a: 21.7247 ± 0.0006 Å
• b: 11.628 ± 0.0003 Å
• c: 20.829 ± 0.0005 Å
• α: 90°
• β: 113.015 ± 0.0008°
• γ: 90°
• Cell volume: 4842.9 ± 0.2 ų
• Cell temperature: 98 K
• Ambient diffraction temperature: 98 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 0.0179
• Weighted residual factors for all reflections included in the refinement: 0.0454
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No