Information card for entry 4326532

Structure parameters

• Formula: C8 H24 F6 N O P3 Si
• Calculated formula: C8 H24 F6 N O P3 Si
• SMILES: P(=N[P+](C)(C)C)(O[Si](C)(C)C)(C)C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Reactions of Phosphine Oxides with Bromophosphoranimines; Synthesis and Unusual Rearrangements of O-Donor Stabilized Phosphoranimine Cations
• Authors of publication: Martin Bendle; Keith Huynh; Mairi F. Haddow; Ian Manners
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 10292 - 10302
• a: 13.9242 ± 0.0017 Å
• b: 10.7663 ± 0.0014 Å
• c: 24.733 ± 0.003 Å
• α: 90°
• β: 104.734 ± 0.002°
• γ: 90°
• Cell volume: 3585.9 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0452
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.0977
• Weighted residual factors for all reflections included in the refinement: 0.1019
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No