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Information card for entry 4326800
Preview
Coordinates | 4326800.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C38 H41 Cl2 Mo2 O9 P S W2 |
---|---|
Calculated formula | C38 H41 Cl2 Mo2 O9 P S W2 |
SMILES | [W](C#[O])(C#[O])(C#[O])(C#[O])[S]([W](P1[Mo]23456789%10([cH]%11[cH]2[cH]3[cH]4[cH]5%11)[c]21[c]6([cH]7[c]8([cH]9[c]%102C(C)(C)C)C(C)(C)C)C(C)(C)C)(C#[O])(C#[O])C#[O])[Mo]1234(C#[O])(C#[O])[cH]5[CH]1[cH]2[cH]4[cH]35.C(Cl)Cl |
Title of publication | A Thiophosphinidene Complex as a Vehicle in Phosphinidene Transmetalation: Easy Formation and Cleavage of a P-S Bond |
Authors of publication | Belén Alvarez; M. Angeles Alvarez; Inmaculada Amor; M. Esther García; Miguel A. Ruiz |
Journal of publication | Inorganic Chemistry |
Year of publication | 2011 |
Journal volume | 50 |
Pages of publication | 10561 - 10563 |
a | 11.2072 ± 0.0004 Å |
b | 14.6547 ± 0.0005 Å |
c | 14.7204 ± 0.0005 Å |
α | 102.093 ± 0.002° |
β | 109.525 ± 0.002° |
γ | 105.085 ± 0.002° |
Cell volume | 2080.07 ± 0.14 Å3 |
Cell temperature | 100 ± 0.1 K |
Ambient diffraction temperature | 100 ± 0.1 K |
Number of distinct elements | 8 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0401 |
Residual factor for significantly intense reflections | 0.0273 |
Weighted residual factors for significantly intense reflections | 0.0487 |
Weighted residual factors for all reflections included in the refinement | 0.052 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.03 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4326800.html
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Users of the data should acknowledge the original authors of the
structural data.