Information card for entry 4326928

Structure parameters

• Common name: Gold/Palladium Carbonyl Phosphine Cluster
• Formula: C86 H150 Au2 O26 P10 Pd28.15
• Calculated formula: C86 H150 Au2 O26 P10 Pd28.14
• Title of publication: CO-Induced Formation of an Interpenetrating Bicuboctahedral Au2Pd18 Kernel in Nanosized Au2Pd28(CO)26(PEt3)10: Formal Replacement of an Interior (μ12-Pd)2 Fragment in the Corresponding Known Isostructural Homopalladium Pd30(CO)26(PEt3)10 with Nonisovalent (μ12-Au)2 and Resulting Experimental/Theoretical Implications
• Authors of publication: Evgueni G. Mednikov; Sergei A. Ivanov; Lawrence F. Dahl
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 11795 - 11806
• a: 18.9815 ± 0.001 Å
• b: 17.2569 ± 0.0009 Å
• c: 19.6744 ± 0.001 Å
• α: 90°
• β: 94.834 ± 0.001°
• γ: 90°
• Cell volume: 6421.7 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0245
• Residual factor for significantly intense reflections: 0.0212
• Weighted residual factors for significantly intense reflections: 0.0511
• Weighted residual factors for all reflections included in the refinement: 0.0533
• Goodness-of-fit parameter for all reflections included in the refinement: 0.802
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No