Information card for entry 4327493

Structure parameters

• Formula: C29 H34 Cl N O4 P Rh
• Calculated formula: C29 H34 Cl N O4 P Rh
• SMILES: [Rh]123([P](c4ccccc4)(c4ccccc4)c4ccccc4)([NH]=C(C)C)[CH]4=[CH]1CC[CH]2=[CH]3CC4.Cl(=O)(=O)(=O)[O-]
• Title of publication: Synthesis of [Ag(NHCMe2)2]ClO4 and Its Use as a Source of Acetimine. 1. Synthesis of the First Acetimine Rhodium Complexes and the First Crystal Structure of a Diacetonamine Complex
• Authors of publication: José Vicente; María-Teresa Chicote; Rita Guerrero; Inmaculada Vicente-Hernández; Peter G. Jones
• Journal of publication: Inorganic Chemistry
• Year of publication: 2003
• Journal volume: 42
• Pages of publication: 7644 - 7651
• a: 9.7384 ± 0.0008 Å
• b: 32.027 ± 0.003 Å
• c: 17.5949 ± 0.0014 Å
• α: 90°
• β: 93.951 ± 0.004°
• γ: 90°
• Cell volume: 5474.7 ± 0.8 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0557
• Residual factor for significantly intense reflections: 0.0334
• Weighted residual factors for significantly intense reflections: 0.0815
• Weighted residual factors for all reflections included in the refinement: 0.0902
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No