Information card for entry 4329465

Structure parameters

• Chemical name: (μ~2~-phenylselenido)-tris(μ~2~-phenylsulfido)-bis(triisopropylphosphine) -methyl-di-copper-gallium
• Formula: C43 H65 Cu2 Ga P2 S3 Se
• Calculated formula: C43 H65 Cu2 Ga P2 S2.995 Se1.005
• Title of publication: Trialkylphosphine-Stabilized Copper(I) Gallium(III) Phenylchalcogenolate Complexes: Crystal Structures and Generation of Ternary Semiconductors by Thermolysis
• Authors of publication: Oliver Kluge; Harald Krautscheid
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 6655 - 6666
• a: 12.1909 ± 0.0005 Å
• b: 39.5081 ± 0.0012 Å
• c: 10.7364 ± 0.0004 Å
• α: 90°
• β: 113.241 ± 0.003°
• γ: 90°
• Cell volume: 4751.5 ± 0.3 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0605
• Residual factor for significantly intense reflections: 0.0519
• Weighted residual factors for significantly intense reflections: 0.1345
• Weighted residual factors for all reflections included in the refinement: 0.1398
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No