Information card for entry 4329649

Structure parameters

• Formula: C111 H120 Au8 F18 O7 P7
• Calculated formula: C111 H120 Au8 F18 O7 P7
• SMILES: c1(ccccc1)[P]1([Au]23[Au]4567[Au]([P](c8ccc([P]([Au]9[Au]%10%11([Au]%12([P](c%13ccccc%13)(c%13ccccc%13)c%13ccc1cc%13)[C]9#[C]%12C1(O)CCCCC1)([Au]195([C]7#[C]1C1(O)CCCCC1)[C](C1(O)CCCCC1)#[C]%119)[Au]156([C]4#[C]5C4(O)CCCCC4)[C]%10#[C]1C1(O)CCCCC1)(c1ccccc1)c1ccccc1)cc8)(c1ccccc1)c1ccccc1)[C]2#[C]3C1(O)CCCCC1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].CC(#[O])C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Intensely Luminescent Homoleptic Alkynyl Decanuclear Gold(I) Clusters and Their Cationic Octanuclear Phosphine Derivatives
• Authors of publication: Igor O. Koshevoy; Yuh-Chia Chang; Antti J. Karttunen; Stanislav I. Selivanov; Janne Jänis; Matti Haukka; Tapani Pakkanen; Sergey P. Tunik; Pi-Tai Chou
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 7392 - 7403
• a: 13.8514 ± 0.0005 Å
• b: 16.7051 ± 0.0006 Å
• c: 29.317 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6783.6 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 17
• Hermann-Mauguin space group symbol: P 2 2 21
• Hall space group symbol: P 2c 2
• Residual factor for all reflections: 0.0646
• Residual factor for significantly intense reflections: 0.0603
• Weighted residual factors for significantly intense reflections: 0.1406
• Weighted residual factors for all reflections included in the refinement: 0.1422
• Goodness-of-fit parameter for all reflections included in the refinement: 1.113
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No