Information card for entry 4330418

Structure parameters

• Common name: tpaMesV(N3Ar)
• Formula: C52.5 H56 N7 O V
• Calculated formula: C52.5 H56 N7 O V
• Title of publication: Well-Defined Vanadium Organoazide Complexes and Their Conversion to Terminal Vanadium Imides: Structural Snapshots and Evidence for a Nitrene Capture Mechanism
• Authors of publication: W. Hill Harman; Michael F. Lichterman; Nicholas A. Piro; Christopher J. Chang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 10037 - 10042
• a: 12.894 ± 0.003 Å
• b: 19.227 ± 0.005 Å
• c: 19.88 ± 0.005 Å
• α: 98.938 ± 0.004°
• β: 99.085 ± 0.004°
• γ: 109.141 ± 0.004°
• Cell volume: 4482.8 ± 1.9 ų
• Cell temperature: 105 ± 2 K
• Ambient diffraction temperature: 105 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1758
• Residual factor for significantly intense reflections: 0.0754
• Weighted residual factors for significantly intense reflections: 0.1653
• Weighted residual factors for all reflections included in the refinement: 0.2133
• Goodness-of-fit parameter for all reflections included in the refinement: 0.974
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No