Information card for entry 4331578

Structure parameters

• Formula: C24 H37 N3 Si2 W
• Calculated formula: C24 H37 N3 Si2 W
• SMILES: [W]1234(=Nc5ccccc5)(N([Si](C)(C)C)c5c(N1[Si](C)(C)C)cccc5)[CH2]=[C]2([C]3(=[CH2]4)C)C
• Title of publication: Coupling of an Aldehyde or Ketone to Pyridine Mediated by a Tungsten Imido Complex
• Authors of publication: Hayton, Trevor W.; Boncella, James M.; Scott, Brian L.; Abboud, Khalil A.; Mills, Ryan C.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Journal issue: 25
• Pages of publication: 9506 - 9517
• a: 13.1319 ± 0.0008 Å
• b: 14.0221 ± 0.0009 Å
• c: 15.0036 ± 0.0009 Å
• α: 72.41 ± 0.001°
• β: 84.247 ± 0.001°
• γ: 89.938 ± 0.001°
• Cell volume: 2619 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0434
• Residual factor for significantly intense reflections: 0.03
• Weighted residual factors for significantly intense reflections: 0.0655
• Weighted residual factors for all reflections included in the refinement: 0.0722
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No