Information card for entry 4331755

Structure parameters

• Chemical name: η^2^-[1,1,1,3,3,5,5,5-Octamethyl-2,4-bis(trimethylsilyl)pentasilane- 2,4-diolato]-η^1^-dimethyl-titanium
• Formula: C16 H48 O2 Si7 Ti
• Calculated formula: C16 H48 O2 Si7 Ti
• SMILES: [Ti]1(O[Si]([Si]([Si]([Si](C)(C)C)([Si](C)(C)C)O1)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C)C
• Title of publication: Trisilane-1,3-diolato Complexes of Ti and Zr: Syntheses and X-ray Crystal Structures†
• Authors of publication: Krempner, C.; Köckerling, M.; Reinke, H.; Weichert, K.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 8
• Pages of publication: 3203 - 3211
• a: 10.084 ± 0.0003 Å
• b: 10.1608 ± 0.0003 Å
• c: 15.8011 ± 0.0005 Å
• α: 79.403 ± 0.002°
• β: 88.393 ± 0.002°
• γ: 86.56 ± 0.002°
• Cell volume: 1588.29 ± 0.08 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0275
• Residual factor for significantly intense reflections: 0.0242
• Weighted residual factors for significantly intense reflections: 0.0639
• Weighted residual factors for all reflections included in the refinement: 0.0688
• Goodness-of-fit parameter for all reflections included in the refinement: 1.086
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No