Information card for entry 4332034

Structure parameters

• Chemical name: hydride-phenyldiazene-tetrakis{phenylbiethoxyphosphine}osmium(II) tetraphenylborate
• Formula: C70 H87 B N2 O8 Os P4
• Calculated formula: C70 H87 B N2 O8 Os P4
• SMILES: [OsH]([P](c1ccccc1)(OCC)OCC)([P](c1ccccc1)(OCC)OCC)([P](c1ccccc1)(OCC)OCC)([P](c1ccccc1)(OCC)OCC)[NH]=Nc1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Synthesis and Characterization of Triazenide and Triazene Complexes of Ruthenium and Osmium
• Authors of publication: Albertin, Gabriele; Antoniutti, Stefano; Bedin, Marco; Castro, Jesús; Garcia-Fontán, Soledad
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 9
• Pages of publication: 3816 - 3825
• a: 12.5264 ± 0.0006 Å
• b: 15.1969 ± 0.0007 Å
• c: 18.0865 ± 0.0008 Å
• α: 87.134 ± 0.001°
• β: 83.701 ± 0.001°
• γ: 82.962 ± 0.001°
• Cell volume: 3394.1 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0351
• Weighted residual factors for significantly intense reflections: 0.0567
• Weighted residual factors for all reflections included in the refinement: 0.0591
• Goodness-of-fit parameter for all reflections included in the refinement: 0.864
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No