Information card for entry 4332263

Structure parameters

• Formula: C22 H52 O2 P2 Ru Si2
• Calculated formula: C22 H52 O2 P2 Ru Si2
• SMILES: C[Si]1(C)C[P]([Ru]2(O1)O[Si](C)(C)C[P]2(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Si−N Bond Hydrolysis Furnishes a Planar 4-Coordinate 14-Electron Ru(II) Complex with a Triplet Ground State
• Authors of publication: Walstrom, Amy; Pink, Maren; Caulton, Kenneth G.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 5617 - 5620
• a: 8.3458 ± 0.0017 Å
• b: 9.9 ± 0.002 Å
• c: 10.238 ± 0.002 Å
• α: 93.283 ± 0.005°
• β: 108.668 ± 0.005°
• γ: 112.034 ± 0.005°
• Cell volume: 727.6 ± 0.3 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0227
• Residual factor for significantly intense reflections: 0.0213
• Weighted residual factors for significantly intense reflections: 0.0545
• Weighted residual factors for all reflections included in the refinement: 0.0556
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No