Information card for entry 4333220

Structure parameters

• Formula: C24 H56 Cl2 N2 Os P4 S4
• Calculated formula: C24 H56 Cl2 N2 Os P4 S4
• SMILES: C(P1(C(C)C)=NP(C(C)C)(=[S][Os]2(S1)(Cl)([S]=P(C(C)C)(C(C)C)N=P(C(C)C)(S2)C(C)C)Cl)C(C)C)(C)C
• Title of publication: Synthesis, crystal structures, and reactivity of osmium(II) and -(IV) complexes containing a dithioimidodiphosphinate ligand.
• Authors of publication: Cheung, Wai-Man; Zhang, Qian-Feng; Williams, Ian D.; Leung, Wa-Hung
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 14
• Pages of publication: 5754 - 5762
• a: 9.6186 ± 0.0008 Å
• b: 15.4228 ± 0.0013 Å
• c: 12.8644 ± 0.0011 Å
• α: 90°
• β: 107.589 ± 0.002°
• γ: 90°
• Cell volume: 1819.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0485
• Residual factor for significantly intense reflections: 0.0355
• Weighted residual factors for significantly intense reflections: 0.0652
• Weighted residual factors for all reflections included in the refinement: 0.0691
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No