Information card for entry 4333224

Structure parameters

• Formula: C26 H62 N2 O2 Os P4 S4
• Calculated formula: C26 H62 N2 O2 Os P4 S4
• SMILES: C(C)(C)P1(C(C)C)=NP(C(C)C)(=[S][Os]2(OC)(S1)(OC)[S]=P(C(C)C)(C(C)C)N=P(C(C)C)(S2)C(C)C)C(C)C
• Title of publication: Synthesis, crystal structures, and reactivity of osmium(II) and -(IV) complexes containing a dithioimidodiphosphinate ligand.
• Authors of publication: Cheung, Wai-Man; Zhang, Qian-Feng; Williams, Ian D.; Leung, Wa-Hung
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 14
• Pages of publication: 5754 - 5762
• a: 9.4626 ± 0.0015 Å
• b: 10.1442 ± 0.0016 Å
• c: 19.756 ± 0.003 Å
• α: 90°
• β: 90.433 ± 0.003°
• γ: 90°
• Cell volume: 1896.3 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0406
• Residual factor for significantly intense reflections: 0.0338
• Weighted residual factors for significantly intense reflections: 0.0756
• Weighted residual factors for all reflections included in the refinement: 0.0786
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No