Information card for entry 4333541

Structure parameters

• Formula: C6 Bi2 K9 Mn2 Na3 O99 W20
• Calculated formula: C6 Bi2 K9 Mn2 Na3 O99 W20
• Title of publication: Synthesis, Structures, and Photochemistry of Tricarbonyl Metal Polyoxoanion Complexes, [X2W20O70{M(CO)3}2]12- (X = Sb, Bi and M = Re, Mn)
• Authors of publication: Chongchao Zhao; Choon Sung Kambara; Ye Yang; Alexey L. Kaledin; Djamaladdin G. Musaev; Tianquan Lian; Craig L. Hill
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 671 - 678
• a: 12.446 ± 0.003 Å
• b: 13.089 ± 0.003 Å
• c: 15.723 ± 0.004 Å
• α: 82.883 ± 0.004°
• β: 73.81 ± 0.004°
• γ: 74.75 ± 0.003°
• Cell volume: 2369.6 ± 1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0764
• Residual factor for significantly intense reflections: 0.0584
• Weighted residual factors for significantly intense reflections: 0.1521
• Weighted residual factors for all reflections included in the refinement: 0.1644
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No