Information card for entry 4333727

Structure parameters

• Formula: C22 H29 F5 N4 Si
• Calculated formula: C22 H29 F5 N4 Si
• SMILES: [Si]1(N(C)C)([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)(F)c1c(F)c(nc(F)c1F)F
• Title of publication: Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine
• Authors of publication: Prinson P. Samuel; Amit Pratap Singh; Sankaranarayana Pillai Sarish; Julia Matussek; Ina Objartel; Herbert W. Roesky; Dietmar Stalke
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 1544 - 1549
• a: 9.256 ± 0.001 Å
• b: 10.202 ± 0.001 Å
• c: 13.9106 ± 0.001 Å
• α: 93.48 ± 0.01°
• β: 92.283 ± 0.01°
• γ: 115.677 ± 0.01°
• Cell volume: 1178.5 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0433
• Residual factor for significantly intense reflections: 0.0358
• Weighted residual factors for significantly intense reflections: 0.0872
• Weighted residual factors for all reflections included in the refinement: 0.0909
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes