Information card for entry 4333739

Structure parameters

• Common name: LHL2788
• Formula: C114 H124 Cl4 N10 P8 Ru2
• Calculated formula: C114 H115 Cl4 N10 P8 Ru2
• SMILES: [Ru]123(Cl)([P](c4ccccc4)(c4ccccc4)CC[P]3(CC[P]1(c1ccccc1)c1ccccc1)CC[P]2(c1ccccc1)c1ccccc1)[NH2]Nc1ccccc1.[Ru]123(Cl)([NH2]Nc4ccccc4)[P](c4ccccc4)(c4ccccc4)CC[P]3(CC[P]1(c1ccccc1)c1ccccc1)CC[P]2(c1ccccc1)c1ccccc1.[Cl-].[Cl-].NNc1ccccc1.NNc1ccccc1.NNc1ccccc1
• Title of publication: Base-Induced Dehydrogenation of Ruthenium Hydrazine Complexes
• Authors of publication: Leslie D. Field; Hsiu L. Li; Scott J. Dalgarno; Ruaraidh D. McIntosh
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 1570 - 1583
• a: 12.117 ± 0.011 Å
• b: 27.59 ± 0.03 Å
• c: 34.12 ± 0.03 Å
• α: 90°
• β: 100.23 ± 0.02°
• γ: 90°
• Cell volume: 11225 ± 19 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0354
• Residual factor for significantly intense reflections: 0.0325
• Weighted residual factors for significantly intense reflections: 0.0779
• Weighted residual factors for all reflections included in the refinement: 0.0789
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No