Information card for entry 4333864

Structure parameters

• Formula: C78 H45 Au3 O24 P3 Pt19
• Calculated formula: C78 H45 Au3 O24 P3 Pt19
• SMILES: C(#[O])[Pt]1234567[Au]89([P](c%10ccccc%10)(c%10ccccc%10)c%10ccccc%10)[Pt]%10%11%12%13%142(C#[O])[Pt]2%15%16%17%18%19%20%21%223[Pt]3%23%24%25%264(C#[O])[Au]41([P](c1ccccc1)(c1ccccc1)c1ccccc1)[Pt]1%27%287%13%18(C#[O])[Au]7%12([P](c%12ccccc%12)(c%12ccccc%12)c%12ccccc%12)[Pt]%12%13%18%29%20%27(C#[O])[Pt]%20%19%2641([Pt]14%19%26%27%16%24(C#[O])[Pt]%16%24%30%25(C#[O])[Pt]%255823(C#[O])([C]6%23=O)[Pt]2359%11%15(C#[O])[C]%10(=O)[Pt]6%14%217%135([Pt]5782(C(=O)[Pt]29%107([Pt]7%171%24%2535(C#[O])[Pt]4%302(C%16=O)(C#[O])[Pt]12%27%10(C#[O])C(=O)[Pt]%18%20%191(C#[O])[Pt]%22%29%2668972C#[O])C#[O])C#[O])C#[O])(C#[O])[C]%28%12=O
• Title of publication: Cooperative Effects of Electron Donors and Acceptors for the Stabilization of Elusive Metal Cluster Frameworks: Synthesis and Solid-State Structures of [Pt19(CO)24(μ4-AuPPh3)3]- and [Pt19(CO)24{μ4-Au2(PPh3)2}2]
• Authors of publication: Alessandro Ceriotti; Piero Macchi; Annalisa Sironi; Simona El Afefey; Matteo Daghetta; Serena Fedi; Fabrizia Fabrizi de Biani; Roberto Della Pergola
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 1960 - 1964
• a: 15.5619 ± 0.0016 Å
• b: 21.25 ± 0.002 Å
• c: 18.164 ± 0.002 Å
• α: 90 ± 0.003°
• β: 91.633 ± 0.003°
• γ: 90 ± 0.003°
• Cell volume: 6004.2 ± 1.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.1619
• Residual factor for significantly intense reflections: 0.0783
• Weighted residual factors for significantly intense reflections: 0.223
• Weighted residual factors for all reflections included in the refinement: 0.2389
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No