Information card for entry 4334043

Structure parameters

• Formula: C24 H40 N6 Ru Si3
• Calculated formula: C24 H40 N6 Ru Si3
• SMILES: CN([Si]1(C)C)c2cccc[n]2[RuH]123([n]4c(cccc4)N(C)[Si]3(C)C)[Si](C)(C)N(C)c1cccc[n]21
• Title of publication: Step-by-Step Introduction of Silazane Moieties at Ruthenium: Different Extents of Ru-H-Si Bond Activation
• Authors of publication: Katharine A. Smart; Mary Grellier; Laure Vendier; Sax A. Mason; Silvia C. Capelli; Alberto Albinati; Sylviane Sabo-Etienne
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 2654 - 2661
• a: 9.679 ± 0.0006 Å
• b: 16.069 ± 0.0008 Å
• c: 36.652 ± 0.0018 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5700.6 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0169
• Residual factor for significantly intense reflections: 0.0161
• Weighted residual factors for significantly intense reflections: 0.0393
• Weighted residual factors for all reflections included in the refinement: 0.0398
• Goodness-of-fit parameter for all reflections included in the refinement: 1.11
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No