Information card for entry 4334137

Structure parameters

• Formula: C75 H74 B Cl N O4 Os P3
• Calculated formula: C75 H74 B Cl N O4 Os P3
• SMILES: [Os](C#[O])(Cl)([NH]=Cc1ccc(cc1)C)([P](OCC)(OCC)OCC)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Azo Complexes of Osmium(II): Preparation and Reactivity of Organic Azide and Hydrazine Derivatives
• Authors of publication: Gabriele Albertin; Stefano Antoniutti; Laura Bonaldo; Alessandra Botter; Jesús Castro
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 2870 - 2879
• a: 22.554 ± 0.003 Å
• b: 12.727 ± 0.0019 Å
• c: 23.939 ± 0.004 Å
• α: 90°
• β: 94.797 ± 0.003°
• γ: 90°
• Cell volume: 6847.5 ± 1.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.235
• Residual factor for significantly intense reflections: 0.0714
• Weighted residual factors for significantly intense reflections: 0.1637
• Weighted residual factors for all reflections included in the refinement: 0.24
• Goodness-of-fit parameter for all reflections included in the refinement: 0.966
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No