Information card for entry 4336465

Structure parameters

• Formula: C75 H74 B F24 O3 P2 Rh Si
• Calculated formula: C75 H74 B F24 O3 P2 Rh Si
• Title of publication: POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium
• Authors of publication: Miguel A. Esteruelas; Montserrat Oliván; Andrea Vélez
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 12108 - 12119
• a: 10.1457 ± 0.001 Å
• b: 19.559 ± 0.002 Å
• c: 19.979 ± 0.002 Å
• α: 87.073 ± 0.002°
• β: 88.661 ± 0.002°
• γ: 77.015 ± 0.002°
• Cell volume: 3857.9 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0688
• Residual factor for significantly intense reflections: 0.0498
• Weighted residual factors for significantly intense reflections: 0.1298
• Weighted residual factors for all reflections included in the refinement: 0.1389
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No