Information card for entry 4337718

Structure parameters

• Formula: C24 H32 Cl6 Ge2 N4 P4
• Calculated formula: C24 H32 Cl6 Ge2 N4 P4
• SMILES: [Ge](Cl)(Cl)[Cl-].[Ge](Cl)(Cl)[Cl-].P1(P2[N+]3N(P=C4C=3CCCC4)C3=C2CCCC3)[N+]2N(P=C3C=2CCCC3)C2=C1CCCC2
• Title of publication: N,N'-fused bisphosphole: heteroaromatic molecule with two-coordinate and formally divalent phosphorus. Synthesis, electronic structure, and chemical properties.
• Authors of publication: Kornev, Alexander N.; Sushev, Vyacheslav V.; Panova, Yulia S.; Lukoyanova, Olga V.; Ketkov, Sergey Yu; Baranov, Evgenii V.; Fukin, Georgy K.; Lopatin, Mikhail A.; Budnikova, Yulia G.; Abakumov, Gleb A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 6
• Pages of publication: 3243 - 3252
• a: 12.9608 ± 0.0006 Å
• b: 11.117 ± 0.0005 Å
• c: 23.3096 ± 0.0012 Å
• α: 90°
• β: 100.033 ± 0.001°
• γ: 90°
• Cell volume: 3307.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.045
• Residual factor for significantly intense reflections: 0.0308
• Weighted residual factors for significantly intense reflections: 0.0694
• Weighted residual factors for all reflections included in the refinement: 0.0738
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No