Information card for entry 4337891

Structure parameters

• Chemical name: RhH(dpp3)P(CF3)2BH2P(CF3)2BH3
• Formula: C96 H68 B3 F48 P4 Rh
• Calculated formula: C96 H68 B3 F48 P4 Rh
• Title of publication: Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine-Boranes.
• Authors of publication: Hooper, Thomas N.; Huertos, Miguel A.; Jurca, Titel; Pike, Sebastian D.; Weller, Andrew S.; Manners, Ian
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 7
• Pages of publication: 3716
• a: 23.0154 ± 0.0005 Å
• b: 17.2614 ± 0.0003 Å
• c: 28.0372 ± 0.0009 Å
• α: 90°
• β: 109.424 ± 0.003°
• γ: 90°
• Cell volume: 10504.6 ± 0.5 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0961
• Residual factor for significantly intense reflections: 0.065
• Weighted residual factors for all reflections: 0.1711
• Weighted residual factors for significantly intense reflections: 0.1596
• Weighted residual factors for all reflections included in the refinement: 0.1711
• Goodness-of-fit parameter for all reflections included in the refinement: 0.947
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No